7/22/2023 0 Comments Tbot tio2 core shellYin JB, He L, Gao ZW, Gao LX, Wang B (2009) Facile method for fabricating titania spheres for chromatographic packing. Wang JW, Wang ZD, Sun NR, Deng CH (2019) Immobilization of titanium dioxide/ions on magnetic microspheres for enhanced recognition and extraction of mono- and multi-phosphopeptides. A series of basic and acidic analytes were also separated on the column.īeeram SR, Rodriguez E, Doddavenkatanna S, Li Z, Pekarek A, Peev D, Goerl K, Trovato G, Hofmann T, Hage DS (2017) Nanomaterials as stationary phases and supports in liquid chromatography. The efficiency of the column after the alkali solution treatment still reaches 98,430 plates m −1, which is only about 1.6% lower than that before the alkali solution treatment. The chemical stability of SiO dSiO 2 spheres under alkaline was tested by flushing of a mobile phase at pH 13 for 7 days. SiO dSiO 2 spheres functionalized with C18 were packed into a stainless steel column. The crystal phase of TiO 2 was measured by XRD. The morphology of the particles was characterized by scanning electron microscopy and transmission electron microscopy. By regulating the rate of hydrolysis of TBOT, almost all of the TiO 2 nanoclusters are modified into the pores and the structure of the original SiO 2 core-shell sphere is hardly affected. The results of the DFT calculations demonstrate that the TiO 2 nanoclusters are always first formed in bulk solution and then enter the pores. The pore size distribution of SiO 2 core-shell spheres modified with TiO 2 (SiO dSiO 2) was analyzed by Barrett-Joyner-Halenda (BJH) method and density functional theory (DFT) method, respectively. Based on a detailed study of the hydrolysis process of tetrabutyl orthotitanate (TBOT), TiO 2 nanoclusters were modified inside the pores of SiO 2 core-shell particles instead of the outside.
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7/22/2023 0 Comments Set up command line for macYou won't see the characters as you type. This is the password you use to sign in to your Mac. The Homebrew installation script will ask you to enter your Mac user password. Homebrew provides an installation script you can run with a single command (check that it hasn't changed at the Homebrew site). If Homebrew is not installed, you will see: zsh: command not found: brew Since you'll probably need Homebrew, you might as well let Homebrew install Xcode Command Line Tools for you.įirst, check if Homebrew is already installed. Homebrew can install almost any open-source tool for developers. Most developers need programming languages and utilities that don't come installed on macOS and are not included in the Xcode Command Line Tools package. Homebrew is the popular Mac package manager. This option was only recently added to Homebrew, so many developers are not aware of it. How to Use Homebrew to Install Xcode Command Line ToolsĪs easy as it is to use the command prompt to install Xcode Command Line Tools, I recommend an even easier method: using Homebrew. You should see the following: /Library/Developer/CommandLineTools Verify that you've successfully installed Xcode Command Line Tools: $ xcode-select -p You'll see a confirmation message when installation is complete. It's significantly slower on Mac Intel over a slow Internet connection. Installation takes 8 minutes on a 2021 Mac M1 Mini, with a 100Mbps Internet connection. You'll see a panel that asks you to install Xcode Command Line Tools.Ĭlick 'Install' to begin the download and installation process. You can also enter the command xcode-select -install in the terminal to begin the installation process. I've written elsewhere about How to Open Terminal on MacOS – just click the Spotlight icon in the menu bar and type “terminal.” Running any of these commands in the terminal will bring up a prompt to install Xcode Command Line Tools. git – the save-as-you-go version control system.clang – a compiler that turns source code into an executable program.Here are examples of commands that will trigger a prompt to install Xcode Command Line Tools: How to Install Xcode Command Line Tools from a Command PromptĪpple has made it easy to install Xcode Command Line Tools because certain commands will prompt you to begin installation. Instead, try either of two faster methods. The download will take too long and it will consume unnecessary disk space. I don't recommend installing the full Xcode package unless you're developing software for an Apple device. install Xcode Command Line Tools as part of a Homebrew installation.install Xcode Command Line Tools when triggered by a command.You have three choices to install Xcode Command Line Tools on a Mac: Luckily, the Xcode Command Line Tools package only requires 1.2GB of space on your disk. Programmers have used these tools on Unix operating systems since computing's beginnings, and they serve as the foundation of almost all software development. It's a smaller package for software developers with tools that run on the command line, that is, in the Terminal application. Instead, you'll install Xcode Command Line Tools. If you're not developing software for an Apple device, you won't need the full Xcode application (it requires over 40GB of disk space!). It's not pre-installed, but you can install it from the Apple developer website or the App Store on your Mac. If you are developing software for macOS, iOS, tvOS, and watchOS, you must install the full Xcode application. Developers need to install Xcode Command Line Tools before they can develop software on a Mac.Īpple provides a complete development environment for programmers named Xcode. 7/22/2023 0 Comments Super bomberman 6 romThen, open the archive file in 7-Zip or right click on it and go to 7-Zip -> Extract Files. If you would like to get a proper No-Intro hash from the converted file, use this script. 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Hides all complex processes of knowledge extraction, model development, dimension reduction, variables selection, noise filtering for avoiding overfitted models, and model validation to the user.Brings Entry-Level Personal Knowledge Mining to Excel users with unprecedented ease of model building and ease of model deployment likewise.You will get more power by extended features and you will be supporting its future development.Features & Benefits In any case, there is a clear upgrade path to higher editions once you need them.If you like the Free version, please consider purchasing a paid edition. For differences between the editions, please visit the download section of our website. It provides a fast and unique way for scientists and business users to generate and apply reliable models from low- to high-dimensional noisy data for a wide range of problems.KnowledgeMiner (yX) for Excel scales to your growing modeling needs as it comes in four flavors: The Free version, which is this App Store version, Copper, Silver, and Gold. KnowledgeMiner (yX) for Excel Free is forecasting software, where you can analyze and forecast processes that take place over time, statistical analysis and modeling software to better understand how a complex problem can be described mathematically, and classification software in one tool. It implements outstanding self-organizing modeling algorithms to significantly reduce time-to-deploy of models by the factor of 10 or more compared to other data mining tools. KnowledgeMiner is based on a proven 50-year research history and development of essential concepts in mathematics, statistics, information and computer science, and systems theory. Export your developed models back to Excel to further predict, analyze, and deploy models in the familiar environment of Excel. Start developing predictive models from low to high-dimensional and noisy data of a few up to 50,000 input variables in our Gold Edition. Develop reliable predictive models in only two steps.You know about the value of your data? Find unknown relevant relationships in your scientific, business or personal data easily by sophisticated, forward looking self-organizing knowledge mining methods for prediction, classification, or simulation tasks in various fields.KnowledgeMiner comes with a tutorial and a number of example data and models like World Oil Price prediction and simulation till 2025, monthly Global Warming predictions and What Drives Global Warming, or Reproductive Toxicity prediction of chemicals to help you getting started with your data.KnowledgeMiner (yX) for Excel Free is a knowledge mining tool that works with data stored in Microsoft Excel for building predictive and descriptive models from this data autonomously. KnowledgeMiner (yX) for Excel Free – Entry-Level Knowledge and Data Mining for Everybody.Simple, objective, fast. For more information, see The Flake Scale Parameter example below.įlake size – Specifies the size of the flakes relative to the distance between them. For more information, see The Flake Density Parameter example below.įlake scale – Scales the entire flake structure. Set this to 0.0 to produce a material without flakes. Lower values produce less flakes and higher values produce more flakes. Values above 0.5 are not recommended as they can produce artifacts.įlake density – Specifies the density (number of flakes) for a certain area. When set to 1.0, the flakes are rotated completely randomly with respect to the normal. When set to 0.0, all flakes are perfectly aligned with the surface. The orientation of the flakes is relative to the surface normal. It is not recommended to set this above 0.9 as it may produce artifacts.įlake orientation – Specifies the orientation value or map of the metal flakes. 2 2.4.3 2.8 2.82 2.83 2D animation 3d 3d compositing 3dl 3dlut 3ds 3ds max 3ds max File Management 3d tracking 8k 12 32Bit 101 360 absorption actor actors addon adobe Adobe Bridge adobe premiere aequence after After Effects aifacingratio align alluminum alpha ambient occlusion anatomy angle Animate animate cc animated texture Animation animation mixer anisotropic anisotropy anodized aov aovs append aquatic arch architechtural architectural Architectural Visualization architecture archviz Arch Viz area light armature arnold array artifacts asset assets atlas atmosphere attribute attributes audio autocad autodesk automation automotive axis b3d backdrop backfacing background backup bake baking basic basics batch beginner bevel bezier billboard bitmap blackmagic blend blendcolors Blender blender 3d blending blueprint blueprints blur blurry bodies body bokeh bones boolean bounding bounds box Bridge broken brush brushed brushed metal brute force bug build bump buttons by c c++ Cache call camera cameras camera tracking can't open candela capture car carpaint carpet caustics cc cd character checker child chromakey cinematics clamp colors class classes cloth clothes clothing cloud clut coat code collision color colored colored metal color lookup table color space compile complex composite Compositing concave configure constraint constraints contrast control conversion convex coordinates correct correction course cover cpp crash create create exe cross dissolve cube currency curve custom cycles cycles render data datasmith date daylight ddx ddy Deadline debris debugging declaration deform deformation delay demolition denoise denoiser depth deselect desktop development different directional directory directx dirt disappear discovery displacement display dissolve distance distributed distribution dive diving dof door double driver drivers dust dwg dxr dynamics edge edges edit editable poly editor effect effects elements encoder encoding engine environment erosion error ethernet event executable expand explorer export expression exr external extrude fabric facing facingratio facing ratio fake user fallof falloff farm fbx field file files fine tune finishing fire first fix flash flip flip book flipped float floor flow flow graph fluffy focus fog folder folders font for forward fps frame frames free fresnel frosted full function fur furry Fusion fx game game design gamedev Game Development game engine gaming gamma correction garbage mask generate generator get gi gif git github GitHub Desktop gizmo glass glazing gloss glossiness glsl god god rays google googlefinance google sheets gpu gradient gradientramp grading green greenscreen group groups gui h.264 h.Flake color – Specifies the color or map of the metal flakes.įlake glossiness – Specifies the glossiness value or map of the metal flakes. 7/22/2023 0 Comments Michael haak floridaJanning said that when she contacted the union, its leaders did nothing to help her but did write a letter to Haak’s judge during his misdemeanor case saying he had a “spotless” record. “Our corporate Culture is built upon treating others with mutual respect and dignity, and the events alleged in this situation are inconsistent with the behavior that we require of our Employees,” the statement read. Southwest denied Janning’s allegations, saying “we immediately supported (Janning) by cooperating with the appropriate outside agencies as they investigated.” She said a Southwest manager sent a memo to more than 25 employees “that made baseless allegations” about her flying competency. She also said that on the day she was grounded, the airline stranded her in Denver and the FBI had to book her a United Airlines flight so she could return home to Florida. She was then required to take “unnecessary” flight simulator training before she could work again. Janning said as retaliation for the FBI report, she was grounded for more than three months, costing her part of her salary. “This person will do and say whatever is necessary to obtain a financial windfall. Salnick says this incident never happened and Haak was never sent to a counseling center. Janning believes that’s because he saw a woman was the scheduled co-pilot. She says Haak, a 27-year veteran of the airline, had used his seniority rights the previous day to bump another pilot who had been scheduled to command the flight. The Associated Press doesn’t normally identify people who say they are victims of sex crimes, but Janning through her attorney agreed to the use of her name.Īccording to the lawsuit filed last week in Orange County, Florida, Janning had never met Haak before August 2020, when she was his co-pilot on a flight from Philadelphia to Orlando. The union did not respond to a phone call seeking comment. Haak, a resident of Longwood, Florida, was a Southwest Airlines pilot for 27 years until his retirement. Southwest said it supported Janning and that it would “vigorously defend” itself against the lawsuit. Michael Haak sentenced to 1 year unsupervised probation. Mark Coulson sentenced him to one year of unsupervised probation and a 5,000 fine. Haak’s attorney, Michael Salnick, said Wednesday that his client disrobed only after Janning encouraged him to, never did anything else and that there were no previous incidents. Michael Haak, 60, apologized and expressed remorse for his actions before U.S. He pleaded guilty last year to a federal misdemeanor charge of committing a lewd, indecent or obscene act and was sentenced to probation. She also alleges that the Southwest Airlines Pilots Association conspired with the airline and refused to support her. Christine Janning alleges that Southwest retaliated by grounding her after she reported Michael Haak to the company and the FBI, that it kept him employed despite an alleged history of sexual misconduct and that managers disparaged her in memos. 7/21/2023 0 Comments Dusk to dawn flood lightsIt may be a bit more expensive than other options, but this home security system is much more than just a floodlight. You can also live-stream and record the footage for the utmost safety. It will then ‘lock’ onto the subject, tracking and recording their movements, giving you direct feedback and notifications to your phone. This clever floodlight cam, that has no blind spots, has an “AI Subject Lock and Tracking” function that can recognize when a human is present. The camera on this unit provides a clear 2K full high-definition color resolution, even at nighttime, and can pan left and right at 360 degrees, as well as tilt vertically to 140 degrees.īut that’s not all. It has a small red light to alert intruders that the area is being surveilled, but you can also turn this off if you prefer the light to remain discreet. You can also schedule the lights to come on at any time via the Eufy app on your phone or tablet. The light panels are adjustable so you can turn them whichever way suits you, and the color and brightness of the spotlights adjust automatically depending on the level of natural outside light. To start with, it’s fully waterproof and has not one, but three bright floodlights providing 3,000 lumens of light. It’s also more expensive than some other styles.Īs one of the best outdoor floodlights on our list, the Eufy Security Floodlight Cam 2 Pro has some impressively advanced technology on offer. Size: 6 x 5.5 x 7 inches | Power Source: Hardwired | Watts/Volts: 300 watts, 120 volts | Brightness: 2,250 lumens | Light Beam Angle: 110 degreesįor installation, it needs to be hardwired by a professional (110-240V). Though it’s less expensive than other styles, the manufacturer also offers a one-year warranty for your peace of mind. At 300 watts, it’s not the most energy-efficient floodlight on our list, but since you control the on/off function, you can monitor how much energy you use. The Lithonia floodlight is constructed from a sturdy, durable, and rust-free metal, and has a white finish. The two heads are easily adjustable by hand either up or down or left to right, so you can get the best angle for your space. It’s a wired floodlight which means you’ll need to get it installed professionally, and, to operate it, you’ll have to manually switch it on and off. Plus, this small unit weighs a mere one pound and has a beam angle of 110 degrees. The light has two bright incandescent lights of 2,250 lumens to illuminate any small to medium-sized garden, patio, or driveway. If you’re looking for the best outdoor floodlight on a budget, the Lithonia Lighting 2-Lamp Outdoor Flood Light is worth considering. Size: 7.10 x 8.35 x 6.70 inches | Power Source: Hardwired | Watts/Volts: 24 watts, 110-240 Volts | Brightness: 2,000 Lumens | Light Beam Angle: Not listed Once you have the Bridge, you’ll even be able to work this floodlight with voice-activation via Alexa. If you don’t already have one, you’ll need the Ring Bridge in order to operate it via Wi-Fi (as well as any other Ring devices you may have), which increases the price a bit. The app also allows you to adjust other settings such as the automatic shut-off time. All activity the unit detects will be reported directly to you via a notification on your phone, and you can monitor and adjust its settings from your smart device on the Ring App. Though it must be hardwired by a professional (all installation tools and screws are included, as well as a thorough user manual), this attractive floodlight is weather resistant and you can even customize its motion sensitivity. It features bright dual-head lamps of 2,000 lumens to efficiently illuminate medium-sized spaces, and it has a motion sensor with a 180-degree field of view to detect any movement up to 70 feet away. When it comes to the best outdoor floodlights, the Ring Smart Lighting Floodlight is a winner in our books. It’s not dimmable and needs to be hardwired by a professional. 7/21/2023 0 Comments Notable deathsIf you find this list interesting, check out these lists of famous suicide notes and of these suicidal celebrities who attempted to kill themselves. 2018 Patricia Morison, American actress (Peyton Place, Dressed to Kill, Kiss Me, Kate The King and I), dies at 103. 2018 Dieter Schnebel, German experimental composer (Harley-Davidson, for nine motorbikes and trumpet), dies at 88. You will find famous American suicides below, as well as some by stars from other countries. Remembering Ruth Bader Ginsburg, John Lewis, Kobe Bryant, Chadwick Boseman, Gail Sheehy, Kirk Douglas, Katherine Johnson, Little Richard, Regis Philbin, Mary. 2018 Carol Mann, American golfer (1964 Western Open, 1965 US Open), dies at 77. In short, numerous notable actors, musicians, and other famous professionals have become victims of suicide. What celebrities have committed suicide? This list features recent celebrity suicides, as well as actors who died by suicide long ago, such as Carole Landis. This list also includes information about the methods of committing suicide used by each of these famous people who killed themselves. She became the First Lady of the United States when her husband became the. Jackie Kennedy was a literature editor, photographer, and socialite who was once married to the former American President John F. legend Vin Scully, actors Ray Liotta and Paul Sorvino, and musicians Loretta Lynn and Meatloaf. Birthplace: Southampton, New York, United States. Anthony Bourdain was a beloved celebrity chef, author, and TV personality, and unfortunately, one of famous suicidal deaths on this list of celebs who took their lives. Notable Deaths of 2022 Remembering those who died in 2022, including L.A. The list below shows all celebrity suicides and all other notable people who ended their lives. We remember notables who died in 2022, including Pope Benedict XVI, Barbara Walters, Pele and Franco Harris. An actor or two on this list was also believed to have killed himself, though the results of his death report has been disputed. Some of these famous suicides happened by overdose, as many of those who took their own lives were consumed by depression. From Robin Williams to Swedish DJ Avicii, plenty of rich and famous stars struggle with mental health-among other hardships. To put things into perspective, just check out this complete list of the most famous suicides in history, including a lot of Hollywood suicides. Whether it's a Hollywood celeb or another famous figure, this list of famous suicides goes to show fame doesn't always buy happiness. The additional tools included in Adobe Flash CS3 now provide incredible video manipulation. You may also like to download Adobe Flash CS6 here. All of this is intended to ensure user comfort and convenience. This means that the users can now easily switch between the different programs, have the panels collapsible or keep every panel right in front of you. Owing to the significance of this feature, it remains constant with Adobe Flash CS3 while attempting to make the interface consistent with other programs in the suite. The old ones remain, while the additional ones are intriguing for those of you who are familiar with Illustrator. The Pen tool has now been brought closer to the standard of Illustrator. It also includes ActionScript 3.0 – a newer version of the object-oriented programming language. Consequently, files from Photoshop or Illustrator can easily be imported to Flash, thus making the workflow between these programs smooth and perfect. This amalgamation means that Adobe Flash CS3 can now take its cues from all of these programs. It thus has been seamlessly unified with Adobe Photoshop, Illustrator and other programs that are part of the suite. You heard me! Adobe Flash CS3 has been brought into the family of Adobe Creative Suite. This user-oriented software has multiple and ravishing features that, as compared to the earlier version (Flash 8), are definitely a significant upgrade! Here’s a list of some of the noteworthy changes in the new version: 1) Integrated with the Adobe Creative Suite However, this time there’s just one variant: Adobe Flash CS3 that incorporates all of the exciting features in it for the mavens out there!Īdobe Flash CS3 can create virtually anything that can come up in a designer’s mind be it animations, banner ads or full-length ads, multimedia websites, kiosks, gaming or other programs and effects, etc. Traditionally, all of Flash’s versions had two variants: Professional and Standard. Adobe Flash CS3 Professional Overview 2022 Adobe Flash CS3 that appeared in 2007 is the ninth version of the conventional Flash. Never can its worth be under-estimated, mainly due to the constant improvements that are being incorporated in its newer versions. It is a handy tool that enables craftsmen throughout the world to create all sorts of animations, graphics, and applications for your devices. Adobe Flash is the multimedia software that has always been in close companionship with designers and developers. 7/21/2023 0 Comments Focal utopiaA headphone that looks like a million bucks, yours for the paltry sum of $4000. All-in-all this is a stealth-black sexy build, with terrific materials, and just the right balance of understatement and bling. Outer capsule housing holds connections for the two black Lemo connectors on the headphone's cable, which is terminated at the player end with a high-quality Neutrik 1/4" phone plug. Black metal mesh and matte black plastic outer capsule covers are accentuated by a black anodized driver rear cover ring emblazoned with "Utopia - Beryllium - Fabrique en France." A brushed aluminum grill covers the central rear driver hole. Curvaceous carbon fiber yolks with black-on-black Focal logo attach to the gloss black plastic capsule housing on one end, and slide into the headband through black anodized aluminum headband end fittings. Sumptuous black lamb-skin leather covers ample memory foam ear and headband pads. Oh my, this is a sexy headphone! In my world, killer audio gear is black, and the Utopia is unapologetically, confidently, bad-ass black. Okay Utopia, $4k huh, I'm lookin' at you, this better be good. Second, that's right, Focal's step-down from flagship headphone is already competing head-to-head with the field.and in this present review we'll take a look at their top-of-the-line Utopia ($3999) to see if we're breaking into new territory. On these two points, Focal has nailed it.on a couple of levels! First, and maybe most importantly, the recently reviewed Focal Elear at $999 competes very strongly with all other $1000+ headphones and, to my ears, bests them in terms of over-all balance. A headphone in this category should never feel or appear cheap in any way. In every way from leather pads to carbon fiber parts to high-quality connectors, materials of a $1000+ headphone should be of very high quality.and when the price exceeds $2000 the bar gets even higher. Sure, they're usually excellent in some ways, but for me a flagship headphone should have a strong balance of performance across the board in addition to areas of outstanding sonic character.Īs much as it grates on headphone enthusiasts with normal-sized wallets, flagship headphones are also luxury items and it's perfectly understandable that they're price accordingly.as long as the luxury is really there. They should sound damned good, but historically they all to often have fatal flaws that degrade perceived performance to the point that they really aren't all that much better than some headphones of a much lower price. Über-expensive headphones are the bane of my existence. |